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Aldrich
Tetrapropylammonium perruthenate
330744 -
97%
DOWNLOAD MSDS (PDF)Synonym: TPAP
CAS Number: 114615-82-6
Linear Formula: (CH3CH2CH2)4NRuO4
Molecular Weight: 351.43
MDL number: MFCD00074914
PubChem Substance ID: 24859883
Properties
| Related Categories | Micro/NanoElectronics, Others, Oxidation, Ruthenium, Solution Deposition Precursors, |
| assay | 97% |
| mp | ~160 °C (dec.)(lit.) |
Description
Application
A soluble, nonvolatile, air-stable, mild oxidant which can be used either stoichiometrically or catalytically with a suitable co-oxidant.
Oxidant used to convert N,N′-dihydroxyimidazolidines to nitronyl nitroxide free radicals.1 Oxidation of hydroxyl-substituted tri-n-butylammonium trifluoroborates to aldehydes and ketones without concomitant cleavage of the carbon-boron bond.2,3
Packaging
1 g in glass btl
250 mg in glass btl
Price and Availability
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Safety Information
| Symbol |   GHS03, GHS07 |
| Signal word | Danger |
| Hazard statements | H272-H315-H319-H335 |
| Precautionary statements | P220-P261-P305 + P351 + P338 |
| Personal Protective Equipment | Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges |
| Hazard Codes | O,Xi |
| Risk Statements | 5-8-36/37/38 |
| Safety Statements | 17-26-36 |
| RIDADR | UN 1479 5.1/PG 2 |
| WGK Germany | 3 |
Technical information & documentation associated with this product is available in the Safety & Documentation tab.
Articles
Oxidizing and Reducing Agents
Oxidation and reduction reactions are some of the most common transformations encountered in organic synthesis, and are some of the organic chemist’s most powerful tools for creating novel products. ...
ChemFiles Volume 1 Article 3
Keywords: Organic synthesis, Oxidations, Reductions
References
1. Synlett, 948, (2006)
2. J. Am. Chem. Soc. 128, 9634, (2006) Abstract
3. Synthesis 7, 639-666, (1994)
Synthesis, 639, (1994)
Aldrichimica Acta 23, 13, (1990)
Tetrahedron Lett. 45, 303-308, (2004)
Merck 14,10463
Fieser 14,302 / Fieser 16,325
Structure Index 1, 60:B:1
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